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View Resource Annual Estimates of Global Anthropogenic Methane Emissions: 1860-1994

David Stern and Robert Kaufmann, of the Center for Energy and Environmental Studies at Boston University, provide "the first estimates," by year, of human-made methane emissions from seven sources, including gas flaring, coal mining, and biomass burning. Data are available in ASCII or binary spreadsheet formats, and a graph shows the rise in methane emissions from 1860 to 1994. The site explains...

https://cdiac.ess-dive.lbl.gov/trends/meth/ch4.htm